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BCIT Citations Collection
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- Carbonation in concrete infrastructure in the context of global climate change
- There is nearly unanimous consensus amongst scientists that increasing greenhouse gas emissions, including CO2 generated by human activity, are effecting the Earth’s climate. Increasing atmospheric CO2 emissions will likely increase the rates of carbonation in reinforced concrete structures. However, there is a lack of reliable models to predict the depth of carbonation as a function of time. To address this deficiency, a numerical model involving simultaneous solution of the transient diffusion and reaction equations of CO2 and Ca(OH)2 was developed. The model successfully includes the effects of variations in various properties such as porosity, humidity, temperature, atmospheric CO2 concentrations and chemical reaction rates. The applicability of the model was confirmed after calibration using data from accelerated carbonation experiments, and the model is used to evaluate the possible effects of climate change by inputting various future climate scenarios in Part 2., Peer-reviewed article, Published.
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- How do accelerated carbonation tests affect the natural morphology and transport characteristics of concrete?
- Carbonation in concrete is a natural chemical process by which atmospheric CO2 reacts with calcium oxide in the Ca(OH)2 and CSH phases in hydrated cement paste to form CaCO3. The carbonation rate in the atmosphere is too slow for laboratory testing, and therefore, it is usually accelerated by using relatively higher CO2 concentrations. However, there exists some disagreement as to what CO2 concentration, humidity and temperature should be specified when conducting an accelerated carbonation test. In this study, samples of hydrated cement paste were carbonated at different CO2 concentrations, and analysed using the x-ray diffraction technique. The results show that the morphology of CaCO3 formed at higher CO2 concentrations is different from that of CaCO3 formed at natural concentrations. It should be recognized that the diffusion coefficient measured at higher concentrations will not be exactly the same as that from naturally carbonating concrete due to the formation of these morphologically different products., Article, Published.
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- Modelling the effects of structural cracking on carbonation front advance into concrete
- Concrete structures are almost certain to contain cracks due to different physiochemical mechanisms. The formation of cracks is sure to affect its durability by altering ion and fluid transport properties. This includes the incursion of CO2 into the structure. There presently exists no consensus on how to model the effects of structural cracking on carbonation progress within concrete structures. This paper first examines the concept of effective diffusion based on simultaneous diffusion of CO2 through sound and cracked concrete and then considers a series diffusion concept where CO2 diffuses first into the crack, and then outwards into the sound concrete. It is concluded that the effective diffusion concept is not valid for structurally cracked concrete. Instead, research efforts should be concentrated on developing a two–phase series diffusion model., Peer-reviewed article, Published.